Reflect on the alignment between your skills and attributes and those Essay

Reflect on the alignment between your skills and attributes and those required in commonwealth bank of the accounting profession - Essay Example There is an array of environmental characteristics to which an accountant working with Commonwealth Bank is exposed to. Some of the major operations taking place at the Bank are private and business banking, enterprise and group services, dealing with markets and institutional banking, retail banking service and wealth management. No matter what kind of environmental traits an accountant is exposed to his skills and attributes must be always aligned. To work as an accountant at the Commonwealth Bank one need to have some professional skills as well as some expertise in his or her respective field. In addition to having the basic accounting skills the accountants must also have some other essential skills such as being computer literate and possessing in depth understanding of spreadsheets. As an accountant at Commonwealth one has to deal with petty cash, the investments and bank accounts of other people, so it is necessary that he or she is trustworthy and honest. It is important that the accountant adheres to all the organizational and accounting policies. Commonwealth Bank likes to include individuals in the firm that are good at multitasking. The Commonwealth Bank also likes to include fresh graduates as interns in their team. The reason the Bank likes to welcome new talent is because it wants that minds with new and innovative idea should be the part of the organization and come up with creative new ideas. The firm does not desire for graduates having much experience as interns. All they are looking for are interns willing to work and learn with the bank on a contractual basis. All they require to have is the basic accounting knowledge and computer and presentation skills. Commonwealth Bank may ask its accountants to lead teams for various important projects. They are also required to oversee projects and enforce the policies of the Bank. It will be an advantage for the Bank if the accountant possesses strong communication skills as it will be

Wolfgang Amadeus Mozart Essay Example for Free

Wolfgang Amadeus Mozart Essay Franz Joseph Haydn (1732-1809) and Wolfgang Amadeus Mozart (1756-1791) were the two great figures of the last quarter of the eighteenth century. They were not men of the same generation, but they were contemporaries in the sense that they influenced one another, and there is a kind of likeness about them which makes them belong together as the outstanding representatives of their own particular period. That period, known variously as the Age of Haydn and Mozart, the Viennese Period, or the Classical Period, is susceptible to two interpretations, depending upon whether the emphasis is placed on its relation to the preceding or to the succeeding period. If the relation to the preceding period is to be stressed, the age of Haydn and Mozart should properly be called the Classical Period because it marks the culmination of the principles of monophonic style and pure independent musical form, the growth of which had marked the period of Gluck, Stamitz, and C. P. E. Bach. If, on the other hand, its relation to the succeeding period is to be emphasized, it must be looked upon as a transitional period leading to, or forming the beginning of, the Viennese Period of Beethoven. In the firest case the formal and stylistic perfection of Mozart, and to a less extent of Haydn, is considered as a culmination, as an end in itself; in the second case that perfection is considered as a necessary but secondary step in an evolutionary chain leading to the achievement of a new expressive medium. (Sieghard Brandenburg, 1998) Franz Joseph Haydn was born in Rohrau, lower Austria, on March 31, 1732. As a child he went to live in the house of a relative, Johann Matthias Frankh, who gave him a thorough musical training. Between 1740 and 1748 Haydn was a chorister at St. Stephens Cathedral in Vienna. During that period he earned his living by teaching, playing the harpsichord, and doing hack work, but all the while immersing himself deeply into serious music study. In 1755 he was engaged by Karl Joseph von Furnberg as conductor of his orchestra, for which he wrote various nocturnes and divertimentos. It was during this period that he also created his first string quartets. While employed at the palace of Count Morzin, between 1758 and 1760, he wrote his first symphonies. In 1760 he married Maria Anna Keller, a marriage that proved unhappy from the beginning and soon gave way to a permanent separation. In 1761, Haydn became second Kapellmeister for Prince Paul Anton Esterhazy at his estate in Eisenstadt. When the Esterhazys built a new palace at Esterhaz, Haydn assumed the status of full Kapellmeister (1766) and held this post for almost a quarter of a century. For the many concert and opera performances at Esterhaz, Haydn produced a vast repertory of compositions in virtually every field and form, arriving at full maturity as creative artist. He rarely left Esterhaz, except for occasional visits to Vienna where he met Mozart and became one of his most devoted friends and admirers. In 1790, Haydn withdrew from his Esterhaz post and went to live in Vienna. In 1791 and 1794, Johann Peter Salomon, impresario and violinist, invited him to London to lead orchestral concerts. For these performances Haydn wrote twelve celebrated symphonies now identified as the London or Salomon Symphonies. Back in Vienna after the second visit, Haydn wrote in 1797 a patriotic hymn which became the Austrian national anthem. Between 1798 and 1801 he completed two choral masterworks, The Creation and The Seasons, his first attempts at writing oratorios. He died in Vienna on May 31, 1809, and was buried in the Hundsthurm churchyard; in 1820 his remains were reinterred in the upper parish church of Eisenstadt. (Jay Parini, Brett C. Millier, 1993) HAYDNS CONNECTION WITH THE ESTERHAZY FAMILY Following the disbanding of Count Morzins musical establishment Haydn secured a post in 1761 with the Esterhazy family, thus forming a relationship which was to continue until the end of his life. First as assistant, and then as first chapelmaster, Haydn was given every incentive necessary to the realization of his genius. Prince Esterhazy was a capable amateur, and in such genial surroundings Haydn gradually developed a remarkable orchestra and a group of singers adequate for the performance of dramatic and religious music. (Ralph De Toledano, 1987) The Esterhazy family, at Eisenstadt and later at Esterhazy, maintained one of the most splendid courts in Europe. Music furnished there, as it did all over Germany, a large part of the entertainment. Almost daily concerts of chamber and orchestral music, interspersed with marionette operas and true operas, to say nothing of the regular use of music at religious services, kept the time of the princes musicians completely filled. Life for men like Haydn was a constant round of concerts, performances and rehearsals, for which most of the music must be composed in otherwise unoccupied moments. The routine was broken by the occasional appearance of troupes of traveling musicians and by the removal of the prince, sometimes accompanied by the whole musical corps, to the capital for the winter season. Fortunately for Haydn, the trips to Vienna furnished opportunity both for the dissemination of his own works and for him constantly to renew his acquaintance with the musical life of the city which had become the musical center of the whole of Europe. (James E. Perone, 1995) THE MUSIC OF THE ESTERHAZY PERIOD A list of the music composed by Haydn during the twenty-nine years of his active connection with the Esterhazy family would be far too long to be included here. His compositions ranged over every musical form characteristic of the time: symphonies, operas, Masses, string quartets, piano sonatas, concertos for various instruments with orchestra, and music for numerous other combinations of instruments and voices. The addition of a famous harpist to the musical forces brought forth a series of compositions for harp; having a famous cellist as a member of the orchestra necessitated concertos for cello and orchestra, which Haydn straightway produced; a ball attended by the emperor brought out the whole orchestra with proudly performed new ballroom music. Haydn stood ready to compose, genially and to the best of his lavish ability, music for any occasion. At the death of Prince Esterhazy in 1790, the musical establishment was disbanded, but Haydn retained his title of Kappelmeister, and although he was now free to devote himself to other affairs, he retained an income from his patrons. The story of the rest of his life recounts constantly increasing fame and honor. His works were performed throughout Europe; Naples, Berlin, Madrid, and London were all anxious to hear his latest composition. Pupils flocked to him, and contemporary composers were almost unanimous in acknowledging his greatness. (David Ewen, 2007 ) LONDON: SYMPHONIES AND ORATORIOS Haydns later life was rich in incident, but that aspect must be left to the biographer. The two journeys to London, in 1790-1792 and 1794-1795, during which he composed the twelve great London symphonies, and conceived the desire to compose oratorios, are most important from the historical standpoint. On his first return to Vienna he devoted himself largely to the two oratorios, the Creation, first performed in 1798, and the Seasons, first performed in 1801. In 1803 he made his last public appearance as a conductor, and from then until his death in 1809, in a Vienna conquered by the armies of Napoleon, his life was that of an honored old man gradually succumbing to his infirmities. (Robert L. Marshall, 2003) Work Cited David Ewen. Composers of Yesterday; Kessinger Publishing, 2007 James E. Perone. Musical Anthologies for Analytical Study: A Bibliography; Greenwood Press, 1995 Jay Parini, Brett C. Millier. The Columbia History of American Poetry; Columbia University Press, 1993 Ralph De Toledano. â€Å"Haydn, Beethoven Old Instruments†; National Review, Vol. 39, April 10, 1987 Robert L. Marshall. Eighteenth-Century Keyboard Music; Routledge, 2003 Sieghard Brandenburg. Haydn, Mozart, Beethoven: Studies in the Music of the Classical Period; Clarendon Press, 1998

Socioeconomics and Anti-Sovereignist Sentiment in Les bons débarras :: Film Movies Films Essays

Socioeconomics and Anti-Sovereignist Sentiment in Les bons dà ©barras Considering the maelstrom of sovereignist sentiment in which late 1970s Quà ©bec politics and society were immersed, it seems almost inevitable that Quà ©bec cinema emerging during that time should be examined for some evidence of nationalist ideology. Les bons dà ©barras, directed by Francis Mankiewicz and based on a screenplay by Quà ©bà ©cois novelist Rà ©jean Ducharme, was written in 1977, but first saw theatrical release in 1980. Arriving as it did just as Renà © Là ©vesque’s Parti Quà ©bà ©cois ascended to power on its promise to hold a referendum on sovereignty-association, Les bons dà ©barras is as likely a target as any for a nationalist-perspective analysis. The film demands critical attention for two additional, marginally related reasons. First, it is considered exceptional as one of only a handful of well received Quà ©bec films produced during the so-called tax shelter era. Second, it garnered attention nationally, reversing a trend which had seen Can ada’s film awards and even critical attention directed traditionally to poor-quality, big-budget, English-language productions financed by the tax-shelter (Lamphier, 1981). Cumulatively, these factors make Les bons dà ©barras an attractive film with which to argue larger issues of Canada-Quà ©bec relations and ideas of national identity. Ian Lockerbie (1988) endeavours to construct just such an argument. Lockerbie suggests that despite the lack of any direct reference to nationalist politics in Les bons dà ©barras, the film presents evidence of a "collective identity" which penetrates deeper than consciously revealed symbolism, and which manifests itself in individual identities and anxieties (1988: 122). The film, Lockerbie claims, offers within the cathartic emancipation of individual characters an implicit manifestation of Quà ©bec sovereignism. By basing his analysis on such deeply buried subtext, however, I think Lockerbie ignores the film’s more obvious engagement with contemporary social and economic conditions. Granted, one inevitably risks a certain degree of impudence whenever venturing to assign allegorical meaning to any film as Lockerbie has done. But I would suggest that if Les bons dà ©barras does in fact propose any commentary on Quà ©bec nationalism, it is not sovereignist at all, as Locke rbie argues, but rather offers an admonitory refusal of Quà ©bec ambitions for independence. The goals of the Quà ©bec sovereignism are traditionally idealized, in part, as a shift from the strength historically drawn from the domestic, familial community toward strength to be gained in achieving social and economic self-sufficiency within Canada. Les bons dà ©barras, however, presents a community whose attempts to attain social integrity and economic self-sufficiency have utterly failed, and whose strength must be found only in retreat to the domestic sphere. Socioeconomics and Anti-Sovereignist Sentiment in Les bons dà ©barras :: Film Movies Films Essays Socioeconomics and Anti-Sovereignist Sentiment in Les bons dà ©barras Considering the maelstrom of sovereignist sentiment in which late 1970s Quà ©bec politics and society were immersed, it seems almost inevitable that Quà ©bec cinema emerging during that time should be examined for some evidence of nationalist ideology. Les bons dà ©barras, directed by Francis Mankiewicz and based on a screenplay by Quà ©bà ©cois novelist Rà ©jean Ducharme, was written in 1977, but first saw theatrical release in 1980. Arriving as it did just as Renà © Là ©vesque’s Parti Quà ©bà ©cois ascended to power on its promise to hold a referendum on sovereignty-association, Les bons dà ©barras is as likely a target as any for a nationalist-perspective analysis. The film demands critical attention for two additional, marginally related reasons. First, it is considered exceptional as one of only a handful of well received Quà ©bec films produced during the so-called tax shelter era. Second, it garnered attention nationally, reversing a trend which had seen Can ada’s film awards and even critical attention directed traditionally to poor-quality, big-budget, English-language productions financed by the tax-shelter (Lamphier, 1981). Cumulatively, these factors make Les bons dà ©barras an attractive film with which to argue larger issues of Canada-Quà ©bec relations and ideas of national identity. Ian Lockerbie (1988) endeavours to construct just such an argument. Lockerbie suggests that despite the lack of any direct reference to nationalist politics in Les bons dà ©barras, the film presents evidence of a "collective identity" which penetrates deeper than consciously revealed symbolism, and which manifests itself in individual identities and anxieties (1988: 122). The film, Lockerbie claims, offers within the cathartic emancipation of individual characters an implicit manifestation of Quà ©bec sovereignism. By basing his analysis on such deeply buried subtext, however, I think Lockerbie ignores the film’s more obvious engagement with contemporary social and economic conditions. Granted, one inevitably risks a certain degree of impudence whenever venturing to assign allegorical meaning to any film as Lockerbie has done. But I would suggest that if Les bons dà ©barras does in fact propose any commentary on Quà ©bec nationalism, it is not sovereignist at all, as Locke rbie argues, but rather offers an admonitory refusal of Quà ©bec ambitions for independence. The goals of the Quà ©bec sovereignism are traditionally idealized, in part, as a shift from the strength historically drawn from the domestic, familial community toward strength to be gained in achieving social and economic self-sufficiency within Canada. Les bons dà ©barras, however, presents a community whose attempts to attain social integrity and economic self-sufficiency have utterly failed, and whose strength must be found only in retreat to the domestic sphere.

Latin History

MEXICO ECONOMY Mexico is located in North America and known as United Mexican States. It consists of thirty-one states and a federal district with the capital of Mexico City. It is most populous city in the Earth. The GDP is $1.149 trillion and per capital income is $11,249. the income per capita is $7.310. It is 12th largest economy in the world as measured in Gross Domestic product. The GDP real growth rate is 4.8%. The average annual GDP growth during 1972 to 1981 was 5.5% whereas during 1981-1986 it was only 1.5%. The GDP’s main share is from services 69.4% and the industry captured 26.7%. From Agriculture it is only 3.9%.   The public debt is 23.3% of GDP. Mexico is highly dependent on exports to the United States. The quarter share of the country’s GDP is based on the exports to the United States. Hence the Mexican economy is strongly linked with the U.S. business. The 1994-year is Mexico’s bad year. Of course it starts with acceptance of NAFTA in the year beginning with United States and Canada and ends with dark Christmas with peso devaluation. During the year there are many political problems like Chiapas rebellion, assignations of political leaders. There was such situation the Mexico attacked with the crisis during 1982 and it got recovered by 7 years whereas during 1994 peso devaluation, it takes for 7 months only to get recovery.   During December 19, 1994, the exchange rate is 3.50 pesos per dollar. The consumer demand for goods collapsed. The Mexican interest rate on loans dramatically increased creating a shock in the banking system. Some businesses closed due to increase of market share. The exports increased with high exchange rate TRADE RELATIONSHIP BETWEEN MEXICO AND UNITED STATES 90% of Mexican trade has been put under free trade agreements with over 40 countries. The North American Free Trade Agreement is significant in this regard. 9% of Mexican exports go to the United States and Canada. And imports recognized 65% from these two countries. The exports to Untied States are 88.4% and imports from United States are 68.4%. Mexico is dependent on trade with United States. The U.S. exports to Mexico include electronic equipment, motor vehicle parts and chemicals and in case of Mexican exports to the United States are Petroleum, cars and electronic equipment. Mexico depends more than on U.S. economy whether it may be good or bad. The NAFTA relation between U.S and Mexico completed more than 10 years. Of course, after the peso devaluation, the Mexico economy become stable, perhaps the United States plays major role. Initially, there was a free trade agreement between Canada and United States called Free Trade Agreement during 1988. Thereafter it was included Mexico and fresh agreement is established in the name of NAFTA. It is trilateral agreement. It is an agreement among the United States, Canada and Mexico. The agreement indicates elimination of tariffs of the produced traded in the respective nations i.e. United States, Canada and Mexico. It is planned to phase out tariffs over a period 15 years. Besides the restrictions were said to be removed from many categories, which includes motor vehicles, computers, textiles and agriculture. MEXICO POLITICAL The type of government is Federal republic. Representing political parties are Institutional Revolutionary Party, National Action Party, Party of the Democratic Revolution, Green Ecological Party, Labor party and several small parties. The politics of Mexico are dominated by the three political parties in Mexico i.e. National Action Party (PAN), Party of the Democratic Revolution (PRD) and the Institutional Revolutionary Party (PRI). The recent federal presidential elections were held on July 2, 2006. President Zedillo and president Fox continued with trade liberalization and several FTAs were signed with Latin American and European countries. Thus Mexico became one of the most open countries in the world of trade. Most Important reform during President Fox period is implementation of Freedom of Information laws. With this effect Mexico City and 26 states supposed to fight against corruption. Hence Mexico becomes international model by usage of FOIA laws and enforcement mechanisms. REFERENE: https://www.cia.gov/library/publications/the-world-factbook/geos/mx.html http://countrystudies.us/mexico/65.htm http://web.worldbank.org/WBSITE/EXTERNAL/COUNTRIES/0,,pagePK:180619~theSitePK:136917,00.html http://www.state.gov/r/pa/ei/bgn/35749.htm   

Exploring The Indian Refinery Industry Environmental Sciences Essay

Energy is being an of import gas pedal for the growing of economic system and in the present scenario oil and natural gas are the chief beginnings of energy. India has got limited beginnings of oil and natural gas, so India has to be dependent on Arabian and African Countries, rich in oil and natural gas militias, for supply of the energy. Indian industry is at present transforming, turning at around 14 % per annum which is non sufficient to prolong the increasing demand for energy. In India, over the last two decennaries, The Refining Industry has witnessed enormous growing. This industry celebrates the centennial of the Refinery at Digboi ( one of the oldest refineries ) , the growing in the industry is accompanied by the tremendous development in the autochthonal capablenesss to engineer, apparatus and design mega refinery undertakings. A major designation for growing in Research activities by the refineries and national research labs have been recorded, with the consequence that activities that were traditionally regarded as being in the sphere of Accredited engineering, are being smartly pursued and cost effectual solutions to the industry ‘s demands are being provided based on autochthonal cognize how. In the 2nd half of the Last Decade, the industry has witnessed a sea alteration. Refineries ab initio were fundamentally Hydro planing refineries, the refineries set up by MNC ‘s integrated secondary processing besides. Production of Lubes was besides incorporated in some of the subsequent refineries. In the early 1980 ‘s, in a large manner secondary processing in the signifier of Fluidized Catalytic Cracking was adopted, when speedy sequence of six such units were in set up. This lead to the rule of Hydro checking in the late 1980 ‘s and early 1990 ‘s as the demand for production of more and more in-between distillations decided the pick of processing options. The three new FCC units were set up with the ability to co procedure residue along with VGO. The demand to guarantee quality of the merchandises conforming to specific rigorous specifications, related to environment and public presentation lead to the development of Hydro treating procedure and a figure of undertakings to better the quality of Diesel have either been implemented or are under execution. Increased profitableness and better quality of merchandises has led to a figure of refineries being taking up surveies to analyze their existing constellations and suggest options for the optimisation of rough oil mix and the processing constellation. Coevals of power or integrating with petrochemicals production is farther adding value to the refinery operations and these are being reviewed really earnestly. All this has led to the transmutation of the Indian refineries and the procedure of alteration still continues and the demands of conservationists going more rigorous, the constellations will go on to germinate. The factors driving the alterations in the refinement scenario are a combination of: aˆ? Minimization of residues aˆ? Maximization of value added merchandises aˆ? Improved merchandise quality aˆ? Maximum use of bing assets aˆ? Environmental judicial admissions Refineries in India are already major exporters of petro merchandises. India is mostly importing the rancid assortment of petroleum from Arab because the overall basket is much cheaper than Brent petroleums. Environmental criterions in India are besides allowing higher sulfur content in gasoline and Diesel.2.0 OIL & A ; GAS SECTOR REFORMSRefinery sector was delicensed in 1998New Exploration Licensing Policy ( NELP ) announced by Govt. in 1999. Administered Pricing Mechanism ( APM ) was dismantled from April 2002. Selling of conveyance fuels like Petrol, Diesel & A ; Aviation Fuel is a permitted topic to run into minimal investing of about US $ 0.44 billion in oil and gas sector. 100 % FDI is permitted in Exploration, Refining, Pipelines for both crude oil merchandises & A ; gas and Selling. Planing Commission study on Integrated Energy Policy in August 2006 Oil and gas is expected to be the cardinal drivers of the energy ingestion growing. Faster geographic expedition of full domestic sedimentary basins to augment domestic handiness of oil and gas Improvement in oil and gas recovery degrees Acquisition of equity oil and gas abroad Exploitation of alternate fuel beginnings such as CBM, Gas Hydrates, Hydrogen fuel cell and blending of bio-fuels Care of strategic militias in oil and crude oil In the last few old ages, the Indian refinery sector has witnessed uninterrupted capacity add-onsIndia: Refining CapacityGet downing with the 2003 to 2009, there is immense capacity add-on in the private sector refineries i.e. from27 mmtpa in 2003 to 72.5 mmtpa in 2009, demoing 168 % addition in the capacity add-on, and a just sum of capacity add-on in the populace sector refineries get downing from 89.9 mmtpa n 2003 to stagnancy in the back-to-back two old ages 2004 and 2005 and smaller balls of add-on in the farther old ages, in 2006 entire private sector refinery capacity amounted to 99.4 mmtpa and in 2007 and 2009 105.5 mmtpa. Harmonizing to the XIth twelvemonth program the capacity add-on in the 2012 is targeted to be 235 mmtpa representing 76 mmtpa from private refineries and 159 mmtpa from public refineries, and 302 mmtpa targeted in 2013, with metameric capacities as 202 mmtpa from public refineries and 100 mmtpa from private refineries.3.0 REFINERY PRODUCTION PROCESSRefinery Production ProcessesRefineries typically consist of a figure of parallel and consecutive procedures used to transform rough oil into a scope of concluding merchandises such as gasolene, Diesel, and asphalt. Modern refineries range from the simple to the really complex, though the tendency is towards increased complexness as the demands for higher-quality concluding merchandises addition. In all refineries, including smaller simple refineries, rough oil is foremost distilled into its basic constituents ; these component watercourses are sent for farther transition in the more complex refineries. The most of import distillment proce dures are the rough distillment, and vacuity distillment. Secondary transition processes by and large use thermal or catalytic procedures to farther change over the oil watercourse from distillment. Among the most of import is the catalytic reformist, where the heavy naphtha, produced in the rough distillment unit, is converted to gasolene ; the fluid catalytic cracker ( FCC ) where the gas oil from the vacuity distillment unit is converted ; and the hydrocrackers, which is used to â€Å" check † the molecules of heavy oil watercourses into lighter merchandises such as gas oil. Refineries by and large include process units such as hydro-treaters or hydro-de-sulfurizers to handle merchandises to better their quality. Ancillary units back uping the chief procedure units include rough desalters ( anterior to distillment ) , hydrogen production, non-energy merchandise units ( asphalt, lubricators ) and public-service corporations ( power and steam ) .Flowchart of a Typical Complex RefineryBeginning: Worrell and Galitsky, forthcoming.3.1 ProcedureCracking Treatment Reforming Hydro-treating Polishing Alkylation3.1.1 Crack:Cracking unit consists of one or more tall, thick, bullet-shaped reactors & A ; web of furnaces, heat money changers & A ; other vass. Procedure uses heat & A ; force per unit area to â€Å" check † heavy hydrocarbon molecules into lighter 1s. Fluid catalytic snap Unit ( FCCU ) A or â€Å" cat snap † It ‘s the basic gasoline-making procedure. FCCU converts most comparatively heavy fractions into smaller gasolene molecules utilizing intense heat ( 1,000 deg F ) , low force per unit area & A ; powdered accelerator for speed uping chemical reactions. Hydro snap: A Procedure applies checking rules utilizing different accelerator, somewhat lower temperatures, much greater force per unit area & A ; H for obtaining chemical reactions. Not all refineries employ hydro snap. Cost-effectively converts medium- to heavyweight gas oils into high-value watercourses Catalytic Crack: Very of import procedure in modern refinement. Procedure allows transition of stuff that would usually be burned as fuel ( vacuity gas oil ) into gasolene and distillation ( heating oil & A ; diesel fuel ) . Price difference between residuary fuel oil & A ; gasolene justifies CRU. Typically this procedure yields 50-60 % gasolene, 20-30 % distillation & A ; 30 % butanes3.1.23.1.3 REFORMING:Catalytic Reforming It uses heat, moderate force per unit area & A ; accelerators to turn naphtha ( light, comparatively low-value fraction ) into high-octane gasolene constituents.3.1.4 HYDRO-TREATING:It ‘s a Purifying procedure for sulfur remotion by responding crude oil fraction with H ( which is obtained from CRU or separate H works ) .3.1.5 Refining:Fine-tuning & A ; otherwise bettering merchandises to run into specifications by uniting assortment of watercourses from treating units. Example, in order to do gasolene, refiner would blend naphtha, reformate, catalytic gasolene, alkylate & A ; butane so that mixture has required octane figure, vapor force per unit area, sulfur degree & A ; aromatics content. Unit of measurements for public presentation additives & A ; dyes to separate assorted classs of fuel.3.1.6 ALKYLATION:Iso-butane ( gaseous by-products of checking ) is reacted with either isobutylene or propene to organize complex paraffinA isomers. Chemical reactions take topographic point in presence of hydrofluoric or sulphuric acid accelerators. By combing these molecules octane degree of paraffin isomer or alkylate is increased to around 93-96 octane. Refiners use this procedure to better octane degree of gasolene pool. The liquid signifier of mixture of hydrocarbons is known as Crude oil, dwelling of six parts of C and one portion of H as chemical compounds, carring little sums of sulfur, metals, salts, O and N. The organic compounds which are accumulated under the sea and trapped in sedimentary stones constitute to their formation. These stones are the topographic points where petroleum oil geographic expedition is concentrated. The oil is under force per unit area and if a pipe is pushed into the rig trap, oil flushs out smartly. With the extraction, the force per unit area is diminished, is so unnaturally reinforced by the injection of air or H2O into the reservoir to keep the force per unit area of the rig and force the oil up to the surface. Crude oil constituting of hydrocarbons that are holding variable boiling points so can be sepaprated through the procedure of refinement. â€Å" Refining is a procedure in which rough oil is heated in a vacuity until it evaporates and so allowed to lift up a column. Hydrocarbons liquefy at different temperatures and therefore can be collected at different highs in the distillment column. † Merchandises, with their approximate boiling points are: Petroleum gas ( & lt ; 90 °C ) Naphtha ( 200-350 °C ) ( it is used to do the additives for high-octane based gasoline, and polymeric plastics and carbamide ) Petrol ( 90-200 °C ) ( used to fuel internal burning engines, chiefly vehicular. ) Kerosene ( 350-450 °C ) ( used as an illuminant and cooking fuel in India and other hapless states, and as a infinite heating fuel in industrial states. ) Diesel ( 200 °C ) High velocity Diesel ( It is largely used in diesel-powered vehicles ) Light Diesel ( It is used in diesel engines running at lower velocity chiefly irrigation pumps and coevals sets ) Lubricant ( 650-1000 °C ) ( consists of lubricating oils and syrupy oils used to lubricate traveling parts in industry, cars, railroad engines and passenger cars and marine engines. Furnace oil ( & gt ; 1000 °C ) ( made by thining residuary fuel oil from polishing with in-between distillations such as diesel oil. It is used in boilers, sand traps, furnaces and warmers. LSHS – Low sulfur heavy stock is variant for furnace oil. ) Solid crude oil coke collected at the underside after the liquid fractions are removed. Which are largely used as fuel, but is besides used to do electrodes and dry cell batteries. The proportion of aggregation of these merchandises may change from rough assortment to crude assortment, which are classified as Sweet or sour.3.2 REFINERY ECONOMICSThe refinery economic sciences can be divided into no. of parts such as: Crude slates Refinery constellation Merchandise slates Capacity use Environmental judicial admissions3.2.1 CRUDE Slates:Crude oils have different outputs depending on natural qualities ( denseness measured as API gravitation & A ; sulphur content ) Low API gravitation implies Heavy petroleum oil Typically higher sulfur content makes crude rancid Outputs of automotive fuels with lower octane & A ; Cetane values doing engine knocking & A ; higher emanations Larger output of lower-valued merchandises, like FO ( available at price reduction to crude oil ) Higher investings in secondary processing installations to better outputs to fit merchandise specifications Lower on Refiners penchant & A ; hence price reduction to sweet petroleum High API gravitation sweet petroleum is on diminution & A ; commands premium over rancid petroleums. Costss & A ; payback periods for refinery treating units must be weighed against awaited rough oil costs & A ; projected derived function between visible radiation and heavy petroleum oil monetary values. Crude mix processed by Indian refineries ( PSU ) 52 % high sulfur and 48 % low sulfur petroleum. GRMs ‘ of Indian refineries ( PSU ) soon around USD 6-7/ Bbl while that of private refineries around US $ 10 per barrel3.2.2 REFINERY CONFIGRATIONS:Refiner ‘s pick of petroleum oil is influenced by the type of refinery processing units- Exceeding works ( dwelling of ) CDU & A ; likely Catalytic Reformer to supply octane Outputs from this works closely reflect natural outputs from petroleum processed Typically merely condensates or light sweet petroleum is processed at this type of installation unless markets for heavy fuel oil ( HFO ) are readily & A ; economically available Asphalt workss are exceeding refineries that run heavy petroleum oil because lone involvement is in bring forthing asphalt/ bitumen Cracking refinery Takes gas oil part from CDU ( a watercourse heavier than Diesel fuel, but lighter than HFO ) & A ; breaks it down further into gasolene & A ; distillate constituents utilizing accelerators, high temperature/ force per unit area Coking refinery Procedures residuary fuel, heaviest stuff from CDU & A ; thermally cracks it into lighter merchandises in Coker or Hydrocracker Addition of FCCU or hydro cracker significantly increases output of higher-valued merchandises, like gasolene & A ; diesel oil, leting processing of cheaper, heavier petroleum while bring forthing an equivalent or greater volume of high-valued merchandises Refineries holding big hydro-treating capableness have ability to treat rough oil with higher sulfur content.3.2.3 PRODUCT Slate:Refinery constellation is influenced by merchandise demand in each part. US demand for gasolene is much larger than distillate demand & A ; therefore refineries configured to maximise gasolene production Gasoline gross revenues account about 50 % of demand while distillate gross revenues account less than 30 % of merchandise demand US refineries are configured to treat big per centum of heavy, high sulfur petroleum, produce more of gasolene & A ; lower of HFO US refineries have invested in more complex refinery constellations, which allow usage of cheaper feedstock & A ; higher processing capableness Indian Refineries merchandise slate ( wt % on petroleum ) norms Light & A ; Middle distillates to heavy terminals ratio of 73:27 with maximal portion of Diesel oil.3.2.4 CAPACITY UTILIZATION:Critical constituent of refinement economic sciences is capacity use rate, or how expeditiously the refinement composite is runing in order to retrieve its fixed costs. Spare capacity consequences in increased competition among refiners, which farther eroded refinement borders. Use rate of about 95 % is considered optimal as it allows for normal unopen downs required for care & A ; seasonal accommodations. Refinery capacity is based on designed size of CDU ( frequently referred to as nameplate capacity ) Occasionally, through ascents or de-bottlenecking processs, refineries can treat more petroleum than nameplate capacity for short periods of clip.4.0 Refining CHALLENGECrude Sourcing/Oil SecurityPotential of Crude available is rather less from bing Fieldss in Middle East, Africa and South American states to back up polishing capacity enlargement and sustain capacity use. To increase the potency of handiness of petroleum certain attempts have been made which are: – Attractive New Exploration Licensing Policy ( NELP ) aˆ? 206 oil & A ; gas geographic expedition blocks awarded in 7 unit of ammunitions aˆ? 68 major finds reported aˆ? Investment committednesss of the order of $ 10 billion aˆ? Huge Unexplored land area aˆ? World ‘s biggest deep H2O gas find made in 2002 ( K-G Basin ) – India Hydrocarbon Vision – 2025 aˆ? 100 % geographic expedition coverage of all sedimentary basins by 2025 aˆ? Internationally competitory financial footings aˆ? Alternate beginnings: CBM and Gas HydratesOil Security: Strategic StorageThe oil security is the up step of Storage & A ; Supply Infrastructure. And for this certain things have been taken into history: – Integrated Energy Policy recommended 90 yearss storage of oil imports – Present storage coverage is 74 yearss and will cut down to 63 yearss with addition in the oil imports – Storage capacity augmentation actions have been taken to heighten the entire storage capacity to 78 yearss. – Planned capacity add-on: 8.62 MMT aˆ? 5.33 MMT by ISPRL at Vizag, Mangalore and Padur aˆ? 3.29 MMT at other locations – Strategic storage to supply addl. 12 yearss screenRefinery Configuration/ ComplexityChanging the Feed stocks would diminish the input costof the refineries by: aˆ?Changing the Quality – 0API / Sulfur / Acidity aˆ? Widening of petroleum basket aˆ? Compulsion to co-process feed-stocks of Bio-origin Following Product Mix Improvement aˆ? Turning demand with rigorous merchandise eyeglasses. aˆ? Switching the regional demand aˆ? Large figure of classs aˆ? Upgradation of low value/surplus merchandises – Naphtha to Petrochemicals – Black Oil to Distillates – Pet Coke to PetrochemicalsEnergy Efficiency Improvementaˆ? Energy efficiency can be betterment by usage of – Energy efficient technologies/designs – Energy efficient equipments – Best operation and care patterns aˆ? GHG emanation decrease through energy efficiency betterment aˆ? Close monitoring and timely actions bridge the spread in specific energy ingestion to fit with the planetary best aˆ? Tools applied are: Pinch Technology, Hydrogen Management, Waste Heat Recovery, Steam Power balance ( CogenerationCycle ) aˆ? Increased use of gas in topographic point of conventional liquid fuel5.0 Demand FOR PETROLEUM PRODUCTSThe demand of crude oil merchandises is related to the energy demand of the state, it is a map of degree of activity measured as GDP. India is soon traveling through the major industrial and economic reforms for the intent of incorporating the Indian economic system with the planetary economic system. The major countries of focal point has been identified as hydrocarbons. Policy alterations are planned for the sector to do the industry globally competitory. The reforms bundle are formed and expected to hold high economic growing in the sector, the demand of crude oil based merchandises is expected to turn at a rate of about 7 % .Wide spreads between merchandise demand and autochthonal petroleum handinessWidening spread between merchandise demand and rough production from autochthonal beginnings leads to heavy dependance on Imports. Oil Equity abroad and fresh discoveries under New Exploration & A ; Licensing Policy are assisting to bridge the spread between demand and autochthonal production. There is a demand for immense investings in refinement, grapevines & A ; Marketing substructure5.1 India: PRODUCT DEMAND & amp ; REFINING CAPACITYHarmonizing to the informations provided IOCL: Excess refinement capacity is expected to increase farther by 2030 India will go on to be merchandise excess Import/Export demand for crude/products to be rather significant6.0 OpportunityThe creative activity of extra refinement capacity of about 110 million tones per annum, an investing of about US $ 22 billion will be required, in the close hereafter. With such a phenomenal growing in the sector, so, ample chances and Scopess are at that place for transportation of the engineerings. The engineerings are required for the upgradation of the bottom barrel and run intoing the predominant demands of in-between distillations and bettering the quality of merchandises that make them environment-friendly and globally competitory. New refineries are located at the seashores while the major Centres, which are for the demand of crude oil merchandises are present in the inland topographic points, largely in North/North-West parts. Therefore, the chances for edifice inland refineries in the state are bing. In the field of petro-chemicals forward integrating is besides allowed for the refineries, which are for the merchandises which are better value-addition and environmental friendly, that will open another country for the investings to happen. India holding a strong committedness to prosecute an energy policy and the environmental factors would be taken into consideration. State is following more environmental friendly steps with respects to the use and the quality of fuels. Decrease of lead and benzine in gasolene, decrease of sulfur and betterment of cetane in Diesel are the major steps that are under execution. Such a quality of upgradation of fuels will necessitate the acceptance of latest engineering, which are bound to incure immense investings of around $ 2500 million.India ‘s advantagesIndia holding a immense modesty of trained and extremely skilled work force at a much lower cost as compared to some of the advanced states. Further, a big population base exists and really low per capita ingestion of crude oil merchandises is predominating, India is one of the fast emerging markets. The state has acquired tremendous experience in the field of installing and efficient operation of crude oil refineries from the past 35 old ages. Therefore, the operating cost will be lower as compared to other states and the value-addition in Indian refineries is of a really high order and that the puting up of refineries in India for the domestic market every bit good as for exports would be economically attractive.India as an international refinement finish and emerging Asian refinement hubIndia is poised to be ‘Asian Refining Hub ‘ due to built-in advantages in its economic system, geographic location, altering demographics, locality to high demand Centre of South East Asia and assorted other factors. India has been frontward looking in its thought and the full growing of Indian Refining Sector can be summed up in four distinguishable stages, namelyA A Early stage A A A A ( 1947 – 1969 ) , Development PhaseA A A ( 1970 – 1990 ) , Economic Liberalisation PhaseA ( 1991 – 2005 ) Mega Refining Hub Phase A ( 2006 onwards ) India is steadily emerging as an international finish for oil refinement with investing demands lesser by 25 % – 50 % as compared to its Asiatic opposite numbers. As per the analysis carried out by Deutsche Bank, India is expected to heighten its refinement competency by 45 % in the following 5 old ages. Bing the fifth biggest worldwide state in context of distillment capacity, India enjoys 3 % of the international capacity portion. To travel in front in doing its presence felt strongly in the planetary market, Indian crude oil houses are be aftering to raise their distillment capacity from the bing 149 mtpa to 243 mtpa by FY 2011-12. Cost fight Cost fight driven by lower fabrication rewards Low capital and hard currency operating costs Entree to big, technically skilled fabrication base and work force Autochthonal procuranceBeginning: A T KearneyStrategic location for petroleum sourcing and merchandise exportAdvantage of Economies of graduated table in big scale undertakings, along with experient and competitory building companies. The Autochthonal procurance sets a platform for cost effectual direction. Readily available accomplishment set for puting up and runing refineries with favorite substructure State of the art engineering being adopted for puting up and upgrading refineries with petroleum processing flexibleness and optimized merchandise slate and quality. Tax holidays/SEZs/PCPIRs offer first-class financial government. The Large domestic market every bit good as turning petrochemical industry has offered the following cardinal growing: Soon over 34,500 Retail Mercantile establishments ( IOC over 17,000 ) Crude grapevine – 3987 Km ( 34.5 MMTPA ) , merchandise grapevine 9454Km ( 55.09 MMTPA ) Politician installations at 14 ports locations: 39 positions, 2 flatboat breakwaters, 8 SPMs Increasing figure of participants in spread outing downstream sector Robust refinement borders Lowest capex/opex Downstream regulator in topographic point Low per capita oil ingestion at 111 kgoe

Adversity in the Ministry

Adversity in the Ministry Free Online Research Papers As a pastor, you have to realize that ministry can be like walking on eggs at times. It does not matter what size church you might be part of, the problems you will have to deal with, will basically be the same. They are the same problems faced in the churches of the New testament. At some point, you will have to address issues of leadership, gossip, doctrine, immorality, lack of help, lack of finances and even color schemes. They might look a little different in each church setting, but are issues that had to be dealt with from the earliest times. The issues in their selves do not matter, but how you handle them means everything. How you come to handle adversity in you ministry can make or break a pastor. Paul is one of the best biblical examples to pattern after. He writes a road map for pastors in his book of Second Corinthians. Every pastor should at some point, study this letter in depth. In the first part of the letter you see Paul going through one of the most nerve wracking ,and make you want to quit, times in his entire life. He is insulted and taunted, accused of not being sincere, being prideful, and boastful. On top of all the insults they attack his preaching, his weaknesses, and call him a deceiver and cheat. Wow! , enough to make you want to turn tale and run. During all this Paul was in a lonely dungeon waiting to be beheaded, but he does not think of his problems or bemoan his lot in life, he only thinks of his beloved church at Cornith. Paul writes to Timothy about leadership and what he is telling Timothy can help all pastors today. In this letter to the Chorenthians Paul gives the New Testament’s best look at what life is like for a minister of the gospel. Paul knew that many of the leaders in Corinth wanted the glory, but only a few wanted to suffer for it, as Christ had. Paul was hurt, because his people, the people he ministered to and discipled, could not see through the self-seeking schemes of those around, trying to persuade them down the wrong path. Paul knew this could damage a church body and was dealing then with issues we still face today. In his book â€Å"Clergy Killers† G.lloyd Rediger says, â€Å"Abuse of pastors by congregations and the breakdown of pastors due to inadequate support are now tragic realities. This worst-case scenario, one that is increasing in epidemic proportions, is not a misinterpretation by a few discontented clergy. Rather,it is a phenomenon that is verified by both research and experience†¦. Pastors have become more vulnerable, parishioners more confused and less courageous, denominational offices more political, and our whole society more numb to abuse and conflict. Together these factors create opportunity for abuse of spiritual leaders and even encourage its development.† Paul faced the same dangers and knew he had to put an immediate stop to the discontent.Even though he loved the people, he knew he had to be firm, â€Å"We are not withholding our affection from you, but you are withholding yours from us.†(2 Corin. 6:12).He loved them dearly, but he loved them so much he could not let them destroy themselves. Philip E.Hughes writes, â€Å"It must be emphasized that Paul is not moved by self-concern he willingly endures for Christ’s sake any number of affronts and indignities to his own person. But when the genuineness of his apostleship is called into question, that is something he dare not endure in silence, for it is no less a challenge to the authority of Christ himself†. (The New International Commentary: second Corin. Page 477) Today our churches are loosing pastors at an alarming rate. What keeps ministers from leaving the ministry? What kind of character does a pastor need to minister to parishioners, who on the most part, love to complain, provoke and ignore? Most pastors stay the course, as Paul did, their emotions might fail them, they might become weary, but their faith in Christ never fails. Two important things are needed in a pastor’s life that helps deal with unwelcome situations, a strong sense of their call and a deep love and concern for their flock. To go along with these two essentials you need to develop strong, godly team leaders, â€Å"Now the overseer must be above reproach, the husband of one wife, temperate, self controlled, respectable, hospitable, able to teach, not given to drunkenness, not violent but gentle, not quarrelsome, not a lover of money. He must manage his own family well and see that his children obey him with proper respect. (If anyone does not know how to manage his own family, how can he take care of the church?) He must not be a recent convert, or he may become conceited and fall under the same judgment as the devil. He must also have a good reputation with outsiders, so that he will not fall into disgrace and into the devils trap.† (1 Tim.3:2-8), having Godly people you can count on will go along way in thwarting adversity. Paul told Timothy; be zealous, be courageous, be faithful and be enduring. Ministry is like being a Farmer; your reward will come at the end, after the work is done. It’s not unusual to want to run from adversity, we are weak in the area of endurance. In your bible, it clearly shows this is not the answer. If this response was practiced many of the dearly loved bible stories would have had a different ending and would have inspired no one. We can not accomplish much that’s worthwhile and not endure opposition. Think for a moment what your parents went through raising you? Anything for our good was â€Å"old fashioned† or â€Å"you just don’t understand† We did not care for anything that was good for us. There is always a purpose for adversity. It’s also two-sided, one side positive; stimulating you to spiritual growth; the opposite side has the potential to defeat and destroy your ministry. Sometimes, the purpose is to keep us humble and our egos in check. The main reason is to grow our trust and faith in God and his ability. When we turn to him, his promise to be our strength will carry us through. The way we respond to adversity shows our true view of God. Many times we ask â€Å"why lord†, sometimes God shows us and sometimes he never makes it known. At times God has to prepare our hearts before he shows us his purpose. Other times adversity comes because of some sin in our lives; pride being the biggest offender. If we search our hearts we can see this might be so and confess and repent; usually the adversity goes with the repentance. Sometimes adversity is the enemy’s doing. In the book of Job (1:6-12) satin brought temptation into Job’s life. Temptations are the underlying factor in much of our troubles. Satin is not allowed, however, to do anything God does not permit. All adversity comes from us, from satin, working around us and in others, or from what God allows in our lives. Nothing happens in our life outside the knowledge of God, who strengthens us to overcome all. Adversity reveals our weaknesses and our strengths. It reveals our willingness to forgive, and it increases our faith in god. Good advice in handling adversity is to face it and not run from it. We can never get far from it, as it always follows, wherever we may run or what church we may try to find. The goal is not to have a problem free ministry; this will never happen. Your goal should be to deal with problems, and problem people, in a biblical manner. Sometimes as pastors, we light the fuse ourselves, because of the way we deal with problems; we need to be skillful and biblical. Adversity is an accurate gage of our spiritual life. If we want to measure our level of faith, we need to look at how we handle our troubles. We need to ask ourselves; how am I handling my circumstances? Am I exhibiting patience, self-control and love? Am I relying on God’s strength and not my own? God has called you to minister to his beloved people; do not be fearful and do not give up. â€Å"So do not fear, for I am with you; do not be dismayed, for I am your God. I will strengthen you and help you; I will uphold you with my righteous right hand.†(Isa.41:10). Works cited Wilson, A.N. Paul, The mind of the Apostle. New York.W.W.NortonCompany Beck,KennethEditor.The NIV Study Bible. Grand Rapids:Zondervan 2002 Bruce, F.F. The New International Commentary on the New Testament: second Corinthians. Grand Rapids Mi.: Eerdmans 1951 Stafford, John, Ministry Burnout.Louisville,Ky.Westminister Press 1992 Williams, Charles D the Christian Ministry and Social Problems. New York. Macmillan Co. 1917. Rediger, G.Lloyd. The Clergy Killers. Louisville, Ky. Westminster Press 1980 Londen, H.B. and Wiseman, Neil B. Pastors at Greater Risk. Ventura, Cal. Gospel Light Regal Books 2003 Research Papers on Adversity in the MinistryBringing Democracy to AfricaQuebec and CanadaThe Project Managment Office SystemAssess the importance of Nationalism 1815-1850 Europe19 Century Society: A Deeply Divided EraInfluences of Socio-Economic Status of Married MalesDefinition of Export QuotasRelationship between Media Coverage and Social andComparison: Letter from Birmingham and CritoAnalysis of Ebay Expanding into Asia

TERROISM UNIT 9 Essay Example

TERROISM UNIT 9 Essay Example TERROISM UNIT 9 Essay TERROISM UNIT 9 Essay Terrorism Name: Course: Institution: Tutor: Date: Terrorism The Impact of Terrorism on the Police Mission Terrorists attacks in the U.S have made a significant different in many departments of the federal. The security department is the most affected. The police department in specific has had to come up with several policies and make a few changes in order to make the significant impact. Concerning the police mission, they are now more careful and more analytical in every case or suspicion they handle (The Council of State Governemnts, 2005). They are no longer only analytical with the immigrants only, but now they are also analytical on the citizens. This is because some attacks have been made by the U.S citizens. To the police, every body is a suspect and capable of either carrying out or facilitating a terrorist attack. Although the terrorist attacks are more serious than the local deaths as they lead to more deaths and casualties, the crimes performed in the neighborhood or locally are taking longer to solve. The police are paying too much attention to the big crimes and overlooking some things that lead to the small crimes. Unlike in the past decades, today, special units have been set aside to specialize in terrorist activities, which include terrorist, groups, threats and those countries that are hosts to terrorist groups such as the Middle East countries (Bayley Perito, 2010). Nowadays, the police department has put it upon itself to monitor the immigrants more critically than before. The monitoring is more critical on the immigrants from the Arab countries or countries that are considered a threat to the U.S. The police mission is to protect all the people of the United States. For this case, there are security issues that have been emphasized as compared to other issues especially after the 9/11 attack. There are more security check-ups, more scrutiny on immigrants and through follow-up on the slightest suspicion of any terrorist threat or activity. Appropriate Law Enforcement Behavior The immigration policy is one of the most prominent arguments relating to the terrorism issues in the United States. The disagreements concern the extent at which the immigrants’ privacy and activities should be monitored. The president argues that the immigrants should be given the same freedom and treatment as the other American citizens, while the other opposing parties argue that there should be stricter policies governing immigration and the immigrants. These include limiting the number of immigrants who are being granted the American citizenship, putting more security at the borders, more scrutiny and vetting at the American embassies before people are given visas to come to the United States amongst other policies ad regulations (Bayley Perito, 2010). It is true that some precautions and regulations interfere with the people’s liberty. For example, the American streets, roads and buildings are filled with cameras. Although it is a protection measure, there are those who argue that too many cameras are interfering with the people’s privacy. In other cases, the concerned federal authorities in charge of security listen to the phone conversations, read the emails and text messages of the people. These extreme measures are more applied on the immigrants who are from the countries hosting terrorist organizations and those being suspected of engaging in suspicious activities. Since the 9/11 attack, stricter measures have been taken (Schulhofer, 2002). However, there are those who argue that these strict measures are affecting particular groups as compared to all the people. Immigrations policies are stricter, limiting the level of legal migration as much as they can, in order to lower the risk of terrorists entering the country. The strict monitoring of the borders and the limiting the level of legal immigration is beneficial. However, these policies should not interfere with the privacy and the liberty of the people of America. This is what the president is putting across. Social Stigma and Police Ethics The social stigma on immigrants from the Arab countries or the people of the Muslim religion has made the police department more careful of their ethical conduct especially after the 9/11 attack (Schulhofer, 2002). Although the police may be tempted to suspect any person from Muslim countries thus being more critical with them as compared to the other countries, it is unethical for them to have legally acceptable reasons when conducting any surveillance or for invading any form of their privacy. There is also a social stigma on the immigrants especially with the ongoing debates concerning the level of legal migration that should be allowed. This area touches on the ethical values of the people. It is ethically required of the police to treat all people, no matter the background, origin, gender or race, in line with their rights, even though they have enough evidence connecting them with a particular criminal act. It is also required of them to follow the right procedures when follow up on a lead concerning a terrorist activity or a suspect (Bayley Perito, 2010). Social stigma has played a role in reducing police corruption. For example, any suspicion of any terrorist activity is being taken seriously as compared to the previous years. In the past, one had to have concrete evidence before any suspected terrorist activity was given the concentration it deserves (The Council of state Governments, 2005). The checks in the airports, train stations and other transport stations were on as severe as it is today. Police were not as careful as they are today. All the immigrants are being fully searched despite their country of origin. Ethical Forces and Police Corruption The ethical forces behind the police corruption are not different with the ethical forces behind the use of police force. The ethical forces concerning police corruption are a matter of how the police conduct themselves. Similarly, the ethical forces behind police force concern the police treatment of the public. Both ways concern the public. For example, the police are required to treat every situation with the seriousness it deserves. The police are asked not to accept any bribes or tokens form the public as a way of motivating them to act. This ethical force requires them to follow the right procedures whether they are dealing with a terrorism case or a case concerning the local crimes (Bayley Perito, 2010). If a member of the public comes in with a claim that he/she has been molested and then another member comes in with a claim that he/she is suspecting a terrorist activity, both cases should be attended. Leaving one case unattended and putting all the concentration on the othe r is not in line with ethical forces. However, the suspicion on terrorist activity may be allocated more resources as compared to the former. Individual Conscience and Police Assignments Police are people who have a conscience just like the rest of the public. Like any other people, they are tempted to act in accordance with their conscience. However, this is against their ethical and professional requirements. For example, they are cannot just start searching someone (invading privacy) because they ‘feel’ that something is not right. They must have tangible evidence. A police officer cannot stop a Muslim citizen or an immigrant from an Arab country because they suspect that he is engaging in terrorism activity. There must be evidence to prove this ‘feeling’ (Bayley Perito, 2010). The individual conscience should not interfere with a police officer’s assignment. The right procedures should be followed and when any arrests or searches are made. This is despite the fact that a police officer may have a few ‘hunches’, connecting the suspect with the activities (Schulhofer, 2002). If they are not legally acceptable, the police officer cannot act entirely on the conscience. However, a police officer can follow up on a lead or a suspicion without interfering with the rights of the individual. If the police find legal reasons warranting of other extreme measures, then they can be taken. Police training on Ethical Dilemmas Police encounter and will continue to encounter ethical dilemmas in the field or in their assignment. This is because there are situations that come where one needs to take either of the extreme measure. If a one fails to know hoe to handle an ethical dilemma when in training, it might harder for the individual to handle it when he/she comes across such a situation. It is therefore significant ethical dilemma training be done before one is released to take up the real life assignments. This can be done by preparing the officers that they will come across cases where they have to choose between bad and good (Bayley Perito, 2010). For example, one might come across a situation where he/she has to shoot a relative, friend, or close family member in order to save victims of a perpetrator. This is if the family member or the relative is the perpetrator. In many cases, people in the police department may be forced to make many sacrifices. Sometimes, these sacrifices involve choosing the public over ones family. It also involves risking the life of one in order to save many. Although this is easier when being theoretically taught than when one practically experiences it, the training prepares the officers psychologically. It is also good for the department to have professional councilors or psychologists so that these officers are well taken care of when such situations come up (Bailey Perito, 2010). References Bayley, D. H., Perito, R. (2010). The police in war: Fighting insurgency, terrorism, and violent crime. Boulder: Lynne Rienner Publishers. Schulhofer, S. J. (2002). The enemy within: Intelligence gathering, law enforcement, and civil liberties in the wake of September 11. New York: Century Foundation Press. The Council of State Governments. (2005). The Impact of Terrorism on State Law Enforcement. Eastern Kentucky University, April.

8 Jobs Where You Can Be Your Own Boss

8 Jobs Where You Can Be Your Own Boss working hard and never seeming to get anywhere? your salary doesn’t stretch that far and there are few raises on the horizon? your coworkers don’t seem to be pulling the same weight you are, and yet you feel totally stuck in the hamster wheel of the working world? maybe it’s time to consider being your own boss for once. this doesn’t need to be a pipe dream. there are careers out there in which you can determine your own salary, work on your own terms, and the sky can be the limit.here are 8 jobs where all this and more could be possible if you work hard enough.1. real estate agentyou’ll need at least a high school diploma, plus a real estate license, but then you can earn an average wage of between $50 and $111k per year. real estate agents work on commission, so the more properties you sell, the more you’ll make. houses, commercial buildings, plots of land, farms, you name it. if you can sell it, you can earn. and remember that commissions will be higher the higher the value of the property. focus on the high-end stuff and start raking it in.2. real estate brokerfor the same amount of education and training, you can make even more money (an average of $80-$167k per year). as a broker, you can sell properties yourself and also manage an agency of other sellers, earning a percentage of their sales and overseeing the business as a whole. in this job, the amount you can earn is almost limitless. start as an agent, and work your way up.3. medical device saleswith a bachelor’s degree- or just a high school diploma, you can earn an average of between $50 and $165k per year. as sales jobs go, this is one of the most complex. it requires a great deal of knowledge of the products, and a great talent for selling things to doctors and medical professionals who are wary of being sold to. you might also have to be trained in demonstrating your products in action. it’s a demanding and competitive field, but can be incr edible lucrative and flexible.4. freelance writingthe education required is utterly negotiable, but the rewards are high. if you have the talent, you have the opportunity to write all over the internet- from blogs to website content to articles, whatever you can find. the first jobs are often the hardest to find, but success builds more and more success.you’ll want to be familiar with blog platforms like wordpress and online media. once you get started, your only limit is the amount of time you can devote to writing more and more pieces.5. insurance sales agentyou’ll need a high school diploma or a bachelor’s degree, but the money can be excellent. some of these jobs pay a fairly standard salary, but some offer a smaller salary and the potential for enormous commissions. you’ll need to put your money where your mouth is and perform, but if you’re up for it, you can really make bank.6. sales manageryou’ll have to work your way up in sales fir st in order to get to this level, but you can nearly double your money if you’re good enough. you’ll manage your own sales team, but also have the ability to make sales on your own in addition. that means commissions for you, plus a percentage of your subordinates’ commissions. you’ll need to be a good leader as well, able to motivate people to perform almost as well as you.7.  personal finance advisoryou’ll need a bachelor’s degree, but you can make anywhere from an average of $118 to $153k per year. this is another job that works mostly on commissions. you’ll have to have a sound financial mind and a knowledge of how the market works, in order to help clients manage their investments, but it can pay off for you as well.8.  sales engineeryou’ll need a bachelor’s degree for this position as well, but the monetary potential is solid. sales engineers sell scientific and tech products to companies and corporations. youà ¢â‚¬â„¢ll need a good base in sales, plus the ability to manage relationships and assert your skills with confidence. public speaking, technical presentations, and sweet talking will stand you in good stead too.so if you’re drudging away for the man and don’t feel you’re earning up to your full potential, consider breaking free of the mold and taking the courageous steps towards building your own self-determined career.

Overview of Mitalio Software Essay Example | Topics and Well Written Essays - 1000 words

Overview of Mitalio Software - Essay Example Moreover, Mitalio also endeavors to offer varied types of inventive software packages in order to enhance the perceived dependency and consistency level of its customers among other competing firms in the market. In order to attain the desired leading position in the international technology industry, the higher authority of Mitalio had decided to offer ERP software packages along with BPM software facilities to enhance its corporate image and identity through innovation in the increasingly competitive industry structure. It was expected by the company officials that this particular strategy would facilitate Mitalio to enhance its total sales along with profitability in the long-run by rewarding its competitive benefits in the short-run processes (Zerio & Nair, 2007). Moreover, to position itself as a market leader in the sector of business software services, the management of Mitalio and its sales team decided to offer more attention to an advertisement and promotional activities. This might prove beneficial for Mitalio to increase the awareness of the customers towards its products, ensuing augmentation of prospective leads and reduction of business threats (Zerio & Nair, 2007). Mitalio is a renowned organization of California which fundamentally attempts to offer cost-efficient software packages to enhance the reliability of its business customers. The prime objective of Mitalio is to augment its supremacy and brand visibility among other apparent players operating within the market. In order to accomplish the underlining desire, the management of Mitalio had decided to offer both BPM and ERP software packages in the international markets of United States, Europe, and Asia.  Ã‚  

Cost and Quality Analysis Essay Example | Topics and Well Written Essays - 1000 words

Cost and Quality Analysis - Essay Example The two are intimately related. However, Brent (1989) explains that there is a certain quality of the health care can lead to lower costs. This is because of the failure of the process to bring a series of high costs. The unit output of the healthcare services is scrapped while the resources used in the production are wasted. In order to recover the scrapped units, additional resources have to be reallocated to the appropriate deficiency. These allocations involve those aimed at replacing the customer who is lost due dissatisfaction in the organization. The organization may also be liable for the additional warranty cost and other damages traced to the failure. Brent (1989) explains that, the lower quality will eventually result to higher costs for the organization. The additional costs arise due to the liability of the process failure caused by the low quality of the services offered to the customer. This situation is termed as Quality waste, which is a representation of the consump tion of resources for repairing the output unit that fails to meet the expectations of the customers. The waste is traced through identification scrap and rework. This is a way of managing and eliminating quality wastage from within the organization aimed to improve the quality of the services. ... Their aim is to focus on the evaluation of the quality of healthcare provided in the hospitals. Buttell, Hendler and Daley (2007), the government has actively engaged in the pursuit of establishing accreditation standards. The other initiative that they are taking is to develop a board recertification to physicians and health care organizations. This is in order to focus on their reporting of the public performance information. These organizations and physicians are to be licensed via multispecialty group practices. An independent agency is established with the roles and responsibilities to review the effectiveness via the public and private partnership. This is aimed at establishing guidelines with standards for the provision of better health care services. Through these agencies, parameters are set about the care that is anticipated to all customers. These parameters include access to medical records, reasonable waiting duration and regularity source of care. The agencies are also focusing on establishing a performance standards aimed at gauging the meeting of the standards. This is in order to regulate the performance of the medical services quality provided to the customers. The agencies are also aimed at separating the generation of the evidence of the translation of the guideline and the anticipated standard. There are initiatives that are focused at improving the quality of services and at the same time incorporating costs control. By the nature of the health care being a process that comprises of series. In order to effect the operations of an institution that provides health care services, the organization should seek to establish

Tata Consultancy Services Limited Assignment Example | Topics and Well Written Essays - 1000 words

Tata Consultancy Services Limited - Assignment Example Tata Consultancy Services Limited The Tata code of conduct says that any employee of Tata should not engage himself/herself in any relationship, business or any such activity that might cause conflict of interest in the company or in Tata group. A situation of conflict of interest can arise directly or indirectly if an employee of the company engages in relationship, activity or business with a party who is transacting with Tata Company or if an employee is taking undue advantage of his position by influences decisions in the company or an independent decision or judgement that cannot best for the group or the company. Interaction of TCS with Financial Market Equity share capital of TCS is traded on BSE and NSE. The company has 1957220996 equity shares with value of 195.72crores traded in the exchange. The company publishes its annual report every year which helps the public and financial market participants to know about the company’s financial and profitability position. It also publishes any news regarding the company’s business operation or any legal changes in the company. The CSR program of TCS includes education, environment and health around the world. It has developed many innovative solutions to solve various societal problems by utilizing their IT competencies. It also provides support for natural disaster relief as their corporate social responsibility. It also engages itself in various community development programs organized by its clients. In 2011-12 year it had engaged itself 58362 hours for corporate social responsibilities and provides help to 5790604 beneficiaries. ... How does TCS view its social obligations and manage its image in society The CSR program of TCS includes education, environment and health around the world. It has developed many innovative solutions to solve various societal problems by utilizing their IT competencies. It also provides support for natural disaster relief as their corporate social responsibility. It also engages itself in various community development programs organized by its clients. In 2011-12 year it had engaged itself 58362 hours for corporate social responsibilities and provides help to 5790604 beneficiaries. The participants of TCS Summit 2013 attended for build a bike for local charity. They participated in the race to build the ultimate bicycle which is human powered and needs no gasoline in Hilton. It was done to help those who are in need of it. Risk Analysis Risk profile of TCS and the amount of overall risk The company operates in large size global market with comparatively low level of penetration gives it significant room for growth in future. They key risks that are faced by TCS are as follows- risks due to global economic situation, redundancy in business model, integration risk in merger and acquisition, risk in supply side, volatility in currency, risk due to protectionism, Anti bribery and compliance and risk due to pressures of cost. Where is this risk coming from and how is the risk profile changing The risks that are faced by TCS mainly come from global market and currency volatility. It also faces some internal risk like risk due to cost pressure of increasing salaries and operating expenses. It also faces challenges which include cultural, technological and financial risks from other firms after

Data and Information System Models Assignment Example | Topics and Well Written Essays - 750 words

Data and Information System Models - Assignment Example Quinn draws attention to several requirements that must be put into consideration in the design phase of a healthcare system for a successful clinical transformation. Among the highlighted requirements presented by Quinn are; accessibility, reliability, security, flexibility, presentation-interface integration, portability and response time. All the presented factors are fundamental and should be looked into when designing healthcare system, however, much focus should be placed on four major factors namely security, accessibility, response to time and reliability (Quinn, 203). Healthcare system is to provide and aid in the management of information with the purpose of implementing clinical transformation. The data and information of patients as well as the doctors and the clinical employees are sensitive and therefore much focus should be place on security of the information entrusted to the system. The system should be designed in a manner that the information stored in it is easily accessible while maintaining integrity of the same information by restricting the access to only thee authorized party. Also, reliability is another factor that should not be overlooked in the design phase given that it is paramount for the success of the system. The designed system should be reliable. Speed is another key factor given that the system should be able to respond fast to the requests by various users since time is a paramount factor in a clinical setting (Quinn, 205). All these factors are critical in strong and appropriate management of information which is in turn imperative in the successful implementation of clinical transformation. At the top of this list is security. The sensitivity of information flowing through clinical and healthcare setting and the need for privacy makes security an imperative factor to consider when designing a healthcare system meant for clinical transformation. Quinn states that it is essential to balance between security and access to in formation in order to successfully secure the system as well as ensuring accessibility to information. Security is ensured within an organization by employing various mechanisms in order to maintain privacy policies. Security plan is composed of both technology components and policy. In order to ensure security and maintain privacy of the information within the system, it is imperative to adopt all-inclusive procedures, policies in addition to educational processes. The technology components of security that should be adopted include access control such as encryption, password/ username, antimalware programs, backup and recovery plans besides physical locks on doors to implement restriction. A secure system ensures that the information stored in the system is reliable, trustworthy and has integrity. Quinn highlights accessibility as another paramount factor to be considered in the successful design of healthcare system for clinical transformation. As much as security is implemented, the same information should be easily available and accessible to the right party at the required time. The users should be able to easily access applications and data within the system in a manner that it does not flout on the security policies of the system. Maintaining the balance between accessibility and security is complicated given that the two factors works against each other in a way. Accessibility works towards

Business Management And Leadership - Planning (U2DB) Essay

Business Management And Leadership - Planning (U2DB) - Essay Example Reachable goals are summarized to be specific, simple, significant, strategic, measurable, rational, tangible, written, shared, and consistent with your values. It is important for an organization to follow these guidelines. In line with this, United Way of America (2008) sets â€Å"three 10-year goals† specifying what their primary goal mentioned above: First, cut down the number of drop out students; second, cut down the number of families who have unstable incomes; and third, increase the percentage of healthy Americans in giving them access to health care benefits. These goals conform to the simple yet straightforward keys to succeed in their attempts to promulgate the cause of the organization. The United Way of America is an organization rapidly growing because they tap all the important sectors in the communities to help them reach their goals. â€Å"So we bring together people from all across the community–government, business, faith groups, nonprofits, the labor movement, ordinary citizens–to tackle the issues† (United Way of America, 2008). The organization knows how significant it is if peoples from all walks of life are able to help one another. It is not just the monetary aspect that can help achieving changing the lives of many. For United Way of America it takes the whole America to help its peoples to come up with solutions, and act out to win their

Organizational Behavior Annotated Bibliography Example | Topics and Well Written Essays - 1000 words - 1

Organizational Behavior - Annotated Bibliography Example Go-To-People are analytical, aggressive, intuitive, humble, patient, confident, deliberate and decisive. In addition they know how well the organization work, know how to use power when it is needed and think outside the box. 3. Go-To-People can be found anywhere in any department of the company and might be very learned or new graduates as well as someone with just formal education. The organization can find them through interviews by asking tricky questions and see how the employees respond. The organization can also find them by looking for talents within the organization. Or creating challenging projects which will help bring out the characteristics of Go-To-People person. 4. Go-To-People should be nurtured by keeping them challenged, recognizing their efforts and rewarding them thus building their career. Usually they work hard but their efforts go unnoticed and this demoralizes them, hence it is necessary for the organization to recognize the value they bring and reward them appropriately. 1. This article describes the ABC model that can be used by managers to obtain desired behavior and performance from employees by providing a positive feedback. The ideas in this article are the A which is ‘action’, B which is ‘because’, C which is ‘could we?’ and finally the conclusion which determines the outcome of the feedback. 2. â€Å"A† focuses on a specific issue and how the feedback conversation should be carried out. This requires data collection first to determine the issue of concern and the managers should be able to raise the topic without provocation or judgment of the employee being addressed. The use of data and facts is important in this step to ensure that both parties have the same information. A proper â€Å"A† statement will lead to a positive feedback. 3. â€Å"B† looks at why the issue in step A is brought up and the need to address it as well as its impact. This involves accountability and the

Business Management And Leadership - Planning (U2DB) Essay

Business Management And Leadership - Planning (U2DB) - Essay Example Reachable goals are summarized to be specific, simple, significant, strategic, measurable, rational, tangible, written, shared, and consistent with your values. It is important for an organization to follow these guidelines. In line with this, United Way of America (2008) sets â€Å"three 10-year goals† specifying what their primary goal mentioned above: First, cut down the number of drop out students; second, cut down the number of families who have unstable incomes; and third, increase the percentage of healthy Americans in giving them access to health care benefits. These goals conform to the simple yet straightforward keys to succeed in their attempts to promulgate the cause of the organization. The United Way of America is an organization rapidly growing because they tap all the important sectors in the communities to help them reach their goals. â€Å"So we bring together people from all across the community–government, business, faith groups, nonprofits, the labor movement, ordinary citizens–to tackle the issues† (United Way of America, 2008). The organization knows how significant it is if peoples from all walks of life are able to help one another. It is not just the monetary aspect that can help achieving changing the lives of many. For United Way of America it takes the whole America to help its peoples to come up with solutions, and act out to win their

Regulating the Employment Relation Case Study Example | Topics and Well Written Essays - 1000 words

Regulating the Employment Relation - Case Study Example According to Working Time Regulation 1998, there is also the question of the total number of hours to be worked. If normal hours are35-40 and all the on-call hours were counted as working hours, the total would be 55-60, so there would need to be an exercise of the opt-out on the part of each employee. However, according to SIMAP, when the worker is in call work tasks will count as working hours. The Working Time Regulations state that working time is "any period during which a worker is working, at his or her employer's disposal and carrying out his or her activity or duties". However to opt-out Joshua few thinks need to consider such as according to statute law in the UK "an employee has the right not to be unfairly dismissed by his employer". But in this case the term of the contract itself unfair. According to Polkey v AE Dayton Services Ltd1, Polkey approach to procedure has however been superseded by the Employment Act 2002. The Act will introduce a new s.98A concerned with statutory dismissal. Before addressing the issue of fairness it will help to put the reasons for dismissal in context. Here there is a dual test; firstly did the employers' decision to dismiss fall with a "band of reasonable responses". Now the test is objective to determine fairness. It is essential to first consider the reason for dismissal before moving on to the concept of fairness. Different considerations apply to these different reasons. If an employer fails to make his reasons clear he will lose his case in the Employment Tribunal as he is unlikely to be able to show that it was potentially fair. Under s98 (1) (b) and s98 (2) Employment Rights Act 1996 the employer must prove that an employee was dismissed for a potentially fair reason. Here there is a dual test; firstly did the employers decision to dismiss fall with a 'band of reasonable responses Post Office v Foly; HSBC Bank v Madden2. Joshua will be given the right to unpaid paternity leave after one year 'subject to the requirements of the business, in the case of British Home Stores v Burchell3, it was held that if an employer held a belief of guilt of an employee, this must be based on reasonable grounds and subject to the employer having carried out as reasonable and practicable investigation into the matter as was possible in the circumstances. Again perhaps amore subjective test would be difficult to find. In Whitbread v Thomas, 4 it was held that the reasonableness of the employers conduct in the dismissal process required compliance with both a pre-dismissal procedure and the appeals process. In Hollister v NFU 5 which viewed procedural matters as merely one of a number of background factors, in the judicial stance towards procedural fairness by adopting what became known as the 'no difference rule. ' In W Devis & Sons v Atkins6 had sought to avoid with regard the reasonableness of the employers conduct and its effect upon the compensation payable. He added that "the British Labour Pump principle appears to have become established in practice without it being appreciated that it represented a fundamental departure from both basic principle and the earlier decisionsit is wrong in principle and undesirable in its practical effect", and that the only test of fairness of a dismissal is the reasonablenes

Traveling Back In Time Essay Example for Free

Traveling Back In Time Essay If there was such a thing as time machine and I could be allowed to travel to any historic epoch as an observer, I would, probably, choose to go million years back, to prehistoric times and Stonehenge. Since my childhood I have been interested in archaeology, early human life and culture, that is why I would not be able to miss this opportunity to see everything I know about prehistoric era with my own eyes. First of all, I would like to see ancient animals, which have now vanished from the earth, including different small and enormous dinosaurs, archaic reptiles-plesiosauruses or flying pterosaurs with huge beaks. It would be absolutely awesome to observe these creatures, along with other elements of ancient flora and fauna, like prehistoric insects or plants, which I had seen before only in books or archaeological museums. Unfortunately, I suppose that it would be almost impossible for me to come into contact and somehow interact with ancient people. But it would be very exciting to take a good look at their life and to learn more about it from own observations. I wonder, how they lived without any industry and manufacturing, government and money, and managed to remain in total harmony with nature, taking from it everything they needed to survive. Finally, I would really love to see, what our mother nature in its absolute purity was like. I can imagine heavy wet smell of air overfilling the body with unbelievable freshness and lightness. Water in rivers must be crystal clean and very tasty. I would try some chemicals-free fruit and enjoy tall emerald-green plants.   After living in our polluted air and trashed environment, this touch of natural beauty would be a miracle, I guess. Certainly, it would be extremely interesting to use time-machine for traveling to the future as well. But what if those horrible things about the future, which they are showing in science fiction movies like The Matrix, will become true? What if artificial intelligence will really become rebellious against the humankind? What will be going on with our nature? Frankly speaking, I would prefer to remain optimistic about the future of people on earth†¦ Bibliography:  ·Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   Wagner, Stephen. Time Travellers. About: Paranormal Phenomena. Ed. About Inc., A part of The New York Times Company. 03 Mar. 2007 http://paranormal.about.com/library/weekly/aa040802a.htm.

Urinary Excretion and Paracetamol

Urinary Excretion and Paracetamol Investigateurinary excretion of paracetamol in man. Paracetamol, known as acetaminophen in the USA, is one of the most commonly used analgesic and antipyretic drugs available over-the-counter. Its common name derives from the full chemical name: para-acetyl-amino-phenol, with the chemical formula C8H9NO2 and amolecular weight of 151.17. Paracetamol does not have anysignificant anti-inflammatory action and therefore cannot be accuratelydescribed as a non-steroidal anti-inflammatory drug (NSAID), as was oncethought. Its mechanism of action is still poorly understood but some studieshave suggested that it inhibits a variant of the cyclo-oxygenase enzyme COX-1, which has been designated COX-3 (Swierkosz et al. 2002). Paracetamol actsmainly in the central nervous system and endothelial cells, rather than inplatelets and immune cells. Boutaud and colleagues (2002) hypothesised thatthis may be explained by the high levels of peroxides found in the latter cell types, which inhibit the action of paracetamol. There has been some debate on thesubject, with other researchers proposing an inhibitory action against COX-2(Graham Scott 2005). Further research is required to fully elucidate the mechanism of action at the molecular level. Metabolism and excretion Following oral administration and absorption from the gastrointestinal tract, paracetamol enters the blood and is distributed throughout the body. It is metabolised by enzymes in the hepatocytes of the liver and the majority is converted to inactive metabolites by conjugation with sulphate or glucuronide. This is then filtered out of theblood by the kidneys and into the urine, via active renal tubular secretion. Asmall portion of paracetamol remains unaltered and passes into the urine viaglomerular filtration and passive absorption (Morris Levy 1984). Thereis also a small proportion of the paracetamol that is metabolised by the thecytochrome P450 system, which results in the formation of cysteine or glutathioneconjugates and mercapturic acid conjugates (figure 2). These products ofoxidative metabolism are also excreted renally (Andrews et al. 1976). Paracetamol has a low therapeuticindex, so the therapeutic dose is very close to the toxic dose. Toxicity canoccur following a single large dose (>10g) or with chronic lower doses(4-5g/d) and is usually seen as hepatotoxicity, which can result in deathwithin several days (Wikipedia). Toxicity occurs when the enzymesresponsible for catalysing sulphate and glucuronide conjugation becomesaturated, forcing metabolism to be increasingly dependent upon the cytochromeP450 system. This results in formation of a toxic metabolite,N-acetyl-p-benzo-quinone imine (NAPQI), which is normally mopped up by bindingto the sulphydryl group of glutathione to form inactive conjugates andmercapturic acid. Toxicity occurs when the glutathione supply becomes exhaustedand NAPQI binds indiscriminately to molecules within the cell, such asmembranes, to cause cell damage and death, seen as acute hepatic necrosis. 1)Major pathway for normal metabolism 2)Minor pathway via cytochrome P450 system produces toxic metabolite (NAPQI),shown in red. Normally this is detoxified by binding to glutathione. 3) Toxicity occurs when pathways 1 and 2 are overloadedand NAPQI binds to molecules of the cell, causing damage. Modifiedfrom Rang et al. 1995. Aim of experiment The aim of this experiment is toinvestigate the renal excretion of paracetamol, by measuring the levels ofparacetamol metabolites in human urine over 6 hours following an oral dose of500mg. The total excretion will be assessed using the spectrophotometricmethod. From this data the elimination rate constant (KE) and thehalf-life (T1/2) will be calculated. Qualitative analysis of thevarious metabolites will be conducted using appropriate chemical identificationtechniques. METHOD A standard stock solution ofparacetamol was prepared at 1mg/cm3 and dilutions were made to givea range of known concentrations. 1 cm3 of the paracetamol solutionwas added to 1 cm3 blank urine and 4 cm3 4M HCl, andmixed thoroughly. A blank duplicate was also prepared, using water instead ofurine. After an hour in a boiling water bath the tubes were cooled and wateradded, up to 10 cm3. 1 cm3 of this hydrolysed urinesolution was added to 10 cm3  of colour forming solution, mixed and allowed to stand for40 minutes. The absorbance of each solution was measured, using thespectrophotometer, zeroing the instrument using the drug free urine sample inbetween solutions. This produced the readings for the calibration curve. Thecollected timed urine samples were then processed in the same way, adding 1 cm3water instead of paracetamol solution. RESULTS AND DISCUSSION Known concentrations of paracetamolunderwent spectrophotometry to measure the absorbance at 620nm. These resultswere used to produce a calibration curve (figure 3). The timed urine sampleswere then analysed following the same protocol and the absorbance at 620nm wasused, in conjunction with the calibration curve to ascertain the concentrationof paracetamol in the urine. Unfortunately, half of the samples producedabsorbances outside the range of the calibration curve. Because this curve isnon-linear, extrapolation and dilution cannot be used to accurately deduce theconcentration of paracetamol in the urine. For the purposes of this report theconcentration for these samples has been declared as greater than 800ug/cm3.This is not very satisfactory and further experiments must be done to extendthe range of the calibration curve to the maximum absorbancy of the timedsamples. The values of KE and T1/2 have been calculatedto demonstrate the procedure, but are inaccurate and will need revisi ng onceaccurate concentrations have been established form the calibration curve. Table 1: Timed urine sample Mean absorbance 620nm Conc. ug/cm3 Vol. Urine (ml) Total drug (ug of paracetamol) Excretion rate mg/h 0 0 0 0 0 0 1 hour 0.256 192 245 47040 47 2 hours 1.918 >800 50 40000 40 3 hours 1.769 >800 38 30400 30.4 4 hours 1.028 >800 55 44000 44 5 hours 0.349 246 135 33210 33.2 6 hours 0.255 192 160 30720 30.7 Table 1 contains the absorbanceresults of the timed urine samples and the deduced concentration of paracetamolin the urine, as well as the hourly excretion rate. The total amount ofparacetamol excreted over the 6 hour period was 225.3mg, which is 45% of theorally administered dose. Due to problems discussed above, this is anunderestimate of the true percentage of dose excreted renally, which has beenfound to be 55-70% by other studies (Steventon et al. 1996). When log of the excretion rate(equivalent to total drug excreted per hour) is plotted against time, a linearplot should be achieved, from which KE can be estimated. The slope of this straight lineequates to : KE /2.303, which gives a value for KE of0.094. Using the formula: T1/2 =0.692/ KE , the valueof T1/2 = 7.36 hours. This states that it takes the body7.36 hours to excrete half of the drug administered. This is longer than the1-4 hours usually quoted for paracetamol (Rang et al. 1995), and is notsurprising given the underestimation of the paracetamol urine concentration.With proper calibration, this would be expected to decrease to nearer thepreviously found results. There were no results for thequalitative studies for metabolite composition, but it would be expected thatsulphate and glucuronide conjugates would constitute the majority of the sample,with a smaller quantity of unchanged paracetamol, cysteine/glutathione andmercapturic acid metabolites. These results only represent oneindividual on one day and replications of this experiment are crucial.Nutritional status, recent alcohol consumption, ethnic background, concurrentdrug usage and illness must all be taken into account as factors that mayaffect paracetamol metabolism and excretion (Riordan Williams 2002, Patel Tang 1992). Further analysis of paracetamolexcretion .  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Hepatotoxicity and drug interactions Table 2 shows how concurrent use of phenobarbital, ananti-epileptic drug, can increase the severity of liver damage caused byparacetamol administration and its subsequent metabolism. Table 2: Effect of Phenobarbital onparacetamol induced hepatotoxicity TreatmentDose of Paracetamol (mg/kg) Severity of liver necrosis None 375 1-2+ Phenobarbital 375 2-4+_________ This occurs due to metabolism ofphenobarbital by enzymes of the P450 cytochrome system, which results inupregulation of their production. As explained in the introduction (see fig.2), P450 enzymes also metabolise paracetamol, to form the toxic metaboliteNAPQI. This is normally a minor pathway but as the amount of P450 enzymesavailable increases, the activity of this pathway also increases. This resultsin a larger than normal amount of NAPQI, which is mopped up and inactivated byglutathione. Glutathione supplies will eventually run out, which occurs soonerif the person is malnourished. When this happens the toxic metabolite binds tocell components, causing necrosis. To prevent this occurring, such as in casesof overdose, N-acetylcysteine can be given (Routledge et al. 1998), which isrequired for glutathione synthesis and helps to boost it. This allows agreater amount of the toxic metabolite to be mopped up and reduces cell damage. .  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Paracetamol metabolism following hepatotoxicity Table 3: Plasmaparacetamol concentrations(ug/cm3) Patients Plasma paracetamol 4 hrs after 12hrsafter Half life (h) ingestion ingestion _______________________________________________________________ noliver damage (18) 2.9 +/= 0.3 163 +/=20 29.5 +/=6 liverdamage (23) 7.2+/= 0.7 296 +/= 26 124 +/=22___ Table 3 shows that, in a study, theability of patients with liver damage to eliminate paracetamol from the bloodis much decreased, compared to healthy people. This is seen by the prolongedhalf-life and the high levels of paracetamol in the plasma. The plasma leveldoes come down by 12 hrs, which indicates that there is enough functional liverreserve to metabolise some of the drug, but the level is still very high. Toascertain whether it is just conjugation that is affected, or whether all thepathways are affected equally it would be necessary to quantify the levels ofdifferent metabolites in the blood and urine. As conjugation is responsiblefor the majority of metabolism, damage to all systems will still show up asaffecting conjugation the most. In theory reduced clearance of asubstance is useful for monitoring the severity of liver damage, but in thecase of paracetamol it would be unwise as it could potentiate the hepatotoxiceffects and worsen the liver condition. It is also unnecessary as there arealready a number of reliable blood tests for liver function and damage. REFERENCES Andrews, R. S., Bond, C. C., Burnett, J., Saunders, A. Watson, K. 1976 Isolation and identification of paracetamol metabolites. J Int Med Res 4,34-9. Boutaud, O., Aronoff, D. M., Richardson, J. H., Marnett, L. J. Oates, J. A. 2002 Determinants of the cellular specificity of acetaminophen as an inhibitor of prostaglandin H(2) synthases. Proc Natl Acad Sci U S A 99,7130-5. Graham, G. G. Scott, K. F. 2005 Mechanism of action of paracetamol. Am J Ther 12, 46-55. Morris, M. E. Levy, G. 1984 Renal clearance and serum protein binding of acetaminophen and its major conjugates in humans. J Pharm Sci 73, 1038-41. Patel, M., Tang, B. K. Kalow, W. 1992 Variability of acetaminophen metabolism in Caucasians and Orientals. Pharmacogenetics 2, 38-45. Rang, H. P., Dale, M.M., Ritter, J.M. 1995 Pharmacology: Churchill Livingstone. Riordan, S. M. Williams, R. 2002 Alcohol exposure and paracetamol-induced hepatotoxicity. Addict Biol 7, 191-206. Routledge, P., Vale, J. A., Bateman, D. N., Johnston, G. D., Jones, A., Judd, A., Thomas, S., Volans, G., Prescott, L. F. Proudfoot, A. 1998 Paracetamol (acetaminophen) poisoning. No need to change current guidelines to accident departments. Bmj 317, 1609-10. Steventon, G. B., Mitchell, S. C. Waring, R. H. 1996 Human metabolism of paracetamol (acetaminophen) at different dose levels. Drug Metabol Drug Interact 13, 111-7. Swierkosz, T. A., Jordan, L., McBride, M., McGough, K., Devlin, J. Botting, R. M. 2002 Actions of paracetamol on cyclooxygenases in tissue and cell homogenates of mouse and rabbit. Med Sci Monit 8, BR496-503. http://en.wikipedia.org/wiki/Paracetamol.